(2R,3S,4S,5R)-5-Hydroxy-2,3,4-tris(phenylmethoxy)-5-[(phenylmethoxy)methyl]-cyclohexanone

Chemical Name:(2R,3S,4S,5R)-5-Hydroxy-2,3,4-tris(phenylmethoxy)-5-[(phenylmethoxy)methyl]-cyclohexanone
CAS Number:911439-19-5
Alternate CAS #:357624-88-5 (+), absolute sterechemistry undetermi
Molecular Formula:C₃₅H₃₆O₆
Molecular Weight:552.66
Category:Research Tools;
Applications:(2R,3S,4S,5R)-5-Hydroxy-2,3,4-tris(phenylmethoxy)-5-[(phenylmethoxy)methyl]-cyclohexanone is used to explore the steric course of 5-epi-valiolone dehydratase in validamycin A biosynthesis. It can also be used to synthesize 1-Silyl-2,6-diketones as versatile intermediates for divergent synthesis of five and six-membered carbocycle cyclitols under radical and anionic conditions.
References:Mahmud, T., et al.: J. Org. Chem., 66, 5066 (2001); Chiara, J., et al.: 8, 3935 (2006)
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